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Why is the second place card the most expensive

1 Infectious Bite

The Gengar in this card is up to no good as its prowling the streets at night, looking for a life to steal

"Prevent all damage done to this Pokemon by attacks from Pokemon-GX and Pokemon-EX during your opponents next turn" - this in itself is incredible against a fully stacked Zoroark GX, Gardevoir GX etc in the first place - but take into account that it can be situationally used in conjunction with the Bonnie 103/131 or 128/131 trainer card which actually allows the GX attack to be used again if played correctly

If Im drafting Rakdos and my neighbor is drafting Simic, we might both be interested in Slitherhead despite having no overlapping colors, and change our draft priorities accordingly